The origin of comets

Our large article about the origin of comets has finally been published! I and my 47 co-authors from Rosetta’s OSIRIS team have made a thorough summary of what we have learned from the spacecraft’s exploration of comet 67P/Churyumov-Gerasimenko, combined with information from other spacecraft and observations of the outer solar system from ground, with the purpose of clarifying which of the previously proposed theories of comet formation that is closest to the truth, and what relation comets have to other types of bodies in the outer solar system. During that process we have realized that none of the earlier theories are fully satisfactory and we propose a new hybrid model that combines elements from earlier hypotheses in a unique manner.

The article has been published in the international scientific journal Astronomy & Astrophysics and can be downloaded here. The European Space Agency ESA, which led the construction of Rosetta and is responsible for the daily operations of the spacecraft and its orbital maneuvers, have also made a short popular summary of the article in their blog, where text and graphics have been produced in collaboration with me.

I will write several blog posts that describes various aspects of this paper. This is the first one which briefly describes earlier theories and our new scenario, step by step. Later posts will focus on different topics: what observations we used; why we consider certain theories inconsistent with those observations; why we were forced to introduce new concepts – and perhaps most important of all – what are the consequences of this new work regarding our understanding of early solar system history?

It has long been known that the interstellar medium, from which new stars and planetary system are made, contains a very large number of dust grains consisting of silicates, sulfides, metals, organic substances, and ice, whose diameters are less than a micrometer (i.e., one part in one thousand of a millimeter). It was also known that the newly formed protosun surrounded itself by a flattened and extensive disk of gas and dust known as the solar nebula, however, the processes that were responsible for transforming this smoke to a planetary system have been less understood. What is really going on when myriads of little grains merge to form large planets like Earth, or beasts like Jupiter? Over the years a number of theories have been proposed, where gravitational instabilities, hierarchical agglomeration (also known as hierarchical coagulation), and streaming instabilities played particularly important roles. They all aim at explaining how planetesimals are formed – small bodies with diameters ranging from a few hundred meters to a thousand kilometers that gradually merge into large planets.

Gravitational instability

This is the oldest model in modern times, that dominated our thinking in the 1960’s. According to this model a sedimentation process occurred in the solar nebula – the small dust grains gradually sunk towards the midplane. The gas disk was rather thick while the dust formed a thinner slab with an ever decreasing thickness. Because of this the density of the dust disk grew large over time, when all grains tried to fit within a comparably small volume. The reason why individual grains moved toward the midplane is the force of gravity emanating from all other grains. However, the dust disk cannot become arbitrarily thin and dense. Calculations of the strength and direction of the gravity field within the dust disk showed that it would break up into a large number of smaller isolated plates once a certain critical density was reached. It was this sudden breakup of the disk into smaller plates that constituted the instability. Under the influence of gravity the plates then collapsed to form spherical planetesimals with sizes of hundreds of kilometers. In this model gravity was therefore solely responsible for transforming the rocky smoke to a planetary system.

Hierarchical agglomeration

Toward the end of the 1970’s people started to question this type of gravitational instability. The solar nebula gas is denser and warmer close to the protosun, but thins out and gets colder at larger distances from it. For this reason a pressure forms in the gas that slightly counters the force of gravity. The result is that the gas disk orbits the protosun at somewhat lower velocity than what a planet at a corresponding distance would have done. We say that the gas has a sub-keplerian motion, while a planet has keplerian motion. However, the dust grains that accumulate in a thinner disk near the midplane does not feel this pressure, which is why the dust moves in a keplerian manner and also forces the gas in its immediate vicinity to do the same. For this reason a layer of dust and gas emerges near the midplane that moves around the protosun with a higher velocity than the gas under and above the midplane. The consequence is well known for those who have seen a wind blow over a calm lake – if the wind is weak nothing happens but if the wind velocity exceeds a critical value ripples form on the surface of the water. The ripples are examples of the Kelvin-Helmholtz instability that arises when two media with different density has sufficiently fast relative shearing velocity. People realized that the Kelvin-Helmholtz instability near the midplane would make the gas there turbulent and that this turbulence prevented the dust disk from becoming sufficiently thin and dense for the gravitational instability to occur. Gravity was simply incapable of forming planetesimals because the turbulence was too strong. It was necessary to search for other mechanisms that did not rely on gravity.

It was realized that the so called van der Waals force could be the solution to the problem. Small dust grains that collide tend to stick together, due to a weak attractive force that arises between molecules in the grain surface layers when in physical contact. If grains merged to ever larger units then planetesimals would grow gradually without the assistance of gravity, at least initially. The process of grain sticking in collisions is called agglomeration and since large planetesimals are formed by mergers between smaller ones their structure forms a hierarchy – the model is therefore often referred to as hierarchical agglomeration.

This model dominated the thinking about planetesimal formation during the 1980’s and 1990’s. Very advanced computer codes were designed to figure out exactly how the hierarchical agglomeration behaved in the complex environment of the solar nebula, where turbulence, gas drag forces (similar to air resistance), material forces and gravity caused the piles of grains to collide, fragment, bounce, and merge on their winding road leading from the solar nebula to a planetary system. On ground, in space shuttles, and in space stations a large number of laboratory experiments were performed aimed at measuring the outcome of collisions between different types of grain clusters at different speeds, so that the computer codes could be fed with data with increasing quality and realism.

The theoretical studies of hierarchical agglomeration showed that the process was very promising – many computer simulations showed that it was possible to form planetesimals in this manner, and that they would have properties that resembled those observed for the asteroids in the belt between Mars and Jupiter, and seen among the large transneptunians in the Edgeworth-Kuiper belt beyond Neptune. However, the experiences were not exclusively positive. One problem was that the process was very slow: the cores of Jupiter, Saturn, Uranus, and Neptune need to reach a certain size before the gas dissipates in the solar nebula when it reaches an age of about 3 million years – otherwise they do not have time to accrete the gas from the solar nebula that they largely consist of. Hierarchical agglomeration did not seem to manage, except during certain conditions. Some imagined that the solar nebula may have contained very large amounts of dust, so that the hierarchical agglomeration proceeded sufficiently fast. That means that a large number of planetesimals remain once the planets have formed – far too many compared to the observed number of asteroids and transneptunians. Possibly this problem could be solved if the planetesimals collided violently with each other at a later stage so that the excess was ground down to sand. This idea was reasonable since the planets gradually changes the orbits of the planetesimals in such a manner that their collisions become increasingly violent. Therefore, it was generally assumed that only the largest bodies in the asteroid belt and the Edgeworth-Kuiper belt had survived more or less intact since the early solar system, while most smaller bodies had formed gradually by the grinding process. Such collision cascades have been studied thoroughly to understand how they function.

Other problems are known as the drift barrier and the bouncing barrier. The drift barrier is a result of the drag forces that act when a small planetesimal try to move at keplerian velocity through the slower sub-keplerian gas and therefore feels a constant air resistance. These drag forces makes the planetesimal spiral toward the protosun. The speed during this sunward drift can reach very high values for bodies with sizes around a meter, while bodies that are either much smaller or substantially larger than this have a significantly slower drift speed. Under certain conditions the meter-sized bodies can drift so fast that the solar nebula quickly looses all its rock, that is completely engulfed by the protosun. The drift barrier means that planets cannot form at all since the construction material disappear completely from the solar nebula early on. Subsequent research has shown that the drift barrier may be breached if the small planetesimals are very porous. Early work on hierarchical agglomeration did not take porosity into account, which is why the drift barrier problem may have been exaggerated. Later laboratory experiment have shown that the mergers of grains at low velocity creates extremely porous bodies. If this is accounted for the drift barrier seems less problematic – there are paths to gradual growth that Nature may have treaded 4.6 billion years ago.

The bouncing barrier is a problem that was discovered during laboratory experiments with dust balls consisting of small silica grains. Those are sufficiently sticky (due to the van der Waals force) that micrometer-sized grains can merge to extremely porous pebbles with diameters ranging millimeters to centimeters. However, at that point the growth grinds to a halt. When the porous pebbles collide with each other they do not merge into larger bodies but just bounce. The planet formation stops at a very early stage if the bouncing barrier is a reality. However, also in this case there seems to be ways around the problem.

Computer simulations are often so extremely complex and time consuming that it is practically necessary to make simplifications to make any kind of progress. However, some of these simplifications may turn out to be fatal. For example, it has often been assumed that the collision between two pebbles (say one with 1 millimeter diameter and another with 2 millimeter diameter) always occur at a certain velocity that is regulated by the dynamics of the two pebbles as determined by the local gravity field and drag forces according to local turbulent conditions. But Nature is never that simple, and it is more likely that such collisions take place with different velocities according to some statistical probability – perhaps 60% of the collisions take place at 1 meter per second, but in 2% of the cases the speed is perhaps just 0.1 meter per second by chance. If one erroneously assume that all collisions are exactly at 1 meter per second – motivated by the majority of cases – this may lead to a bottleneck, or in the worst case, a dead end. But if one allows for a natural spread in collision velocities, it is possible that the unusually low velocities actually allows for a limited growth, that later leads to dramatic consequences for how the entire collective of grains, pebbles, and boulders behave – there is a way around the bottleneck and the planet formation process continues.

Another aspect is that laboratory experiments based on silica grains may be a very realistic analogue for material in the warm inner solar system, but not necessarily for the cold outer solar system. Beyond Jupiter’s orbit it is so cold that the rocky grains are covered by organic substances, ordinary crystalline water ice, and a type of structure in frozen water that only arise when it is formed at extremely low temperature – amorphous water ice. Organic substances and crystalline ice is much stickier than silica grains, and amorphous ice is stickier still. It is extremely difficult to make realistic laboratory experiments with such material. Only in recent years there have been published results from laboratory experiment were icy grains with the right dimensions where produced in a controlled way, and investigations of how their hierarchical growth differs from that of silica has begun. Experiments with organic species are also very few and as far as I know agglomeration experiments with amorphous ice have never been done. Preliminary results indicates that the bouncing barrier may not have existed in the cold region where comets were born.

For these reasons hierarchical agglomerations remains being a viable model, even though there is a healthy dose of skepticism in parts of the scientist community who doubt that agglomeration is the answer to all questions, everywhere. In hierarchical agglomeration is the the van der Waals force that primarily is responsible for turning the solar nebula dust into a planetary system.

Streaming instabilities

In 2005 a theoretical work was presented that showed that gas and pebbles possibly could collaborate in a previously unforeseen way, with the consequence that large dense swarms of pebbles formed in the solar nebula – as soon as such a swarm formed it grew rapidly thanks to the streaming instability. At some point the swarm became so large that its self-gravity managed to collapse the swarm into a large planetesimal. Ten years earlier it would have been impossible to test the theory in a large-scale computer simulation, but at this time the computers were sufficiently fast for such a test to be feasible. In 2007 the first successful test was presented, which was greeted with a lot of curiosity and enthusiasm by the science community – and with quite much relief. Finally a model that seemed to answer all questions, and that was not troubled by a lot of annoying barriers!

In this model hierarchical agglomeration is responsible of building pebbles with diameters ranging 1-10 centimeters. If the number of pebbles is sufficiently large compared to the amount of gas the streaming instability will form large swarms of pebbles, if not only the gas is allowed to modify the pebble’s dynamics, but the pebbles are allowed to change the gas motion as well – this mutual interaction is the key to the streaming instability. This process is very fast – forming a swarm sufficiently large to produce an asteroid as large as Ceres (an object with a 1000 kilometer diameter) takes about 10 revolutions around the protosun. That corresponds to about 50 years in the asteroid belt and about 3000 years in the Edgeworth-Kuiper belt. The gravitational collapse takes just 100 years. Considering that the solar nebula had an expected lifetime of about 3 million years, we understand that planetesimals form very fast. This solves one of the most difficult problems with hierarchical agglomeration – that process is too slow to build planet-sized bodies on a reasonable timescale.

Apart from the short planetesimal formation time this model is also characterized by another property – there is no hierarchical procedure where bodies are built gradually, but they jump directly from one centimeter to 100 or 1000 kilometers, depending on the size of the swarm. In this model van der Waals forces, gas drag, and gravity are all involved in planetesimal formation, but at different stages.

Earlier theories about the origin of comets

I have previously described what a comet nucleus is in a blog post. There has never been a single commonly accepted view on comet formation in the scientist community. Instead, a handful of theories have coexisted, each supported by a number of theoretical works and observations. It has not been possible to single out a specific model for the simple reason that there was not a sufficient amount of observations of real comets to be able to exclude all models except one, that remains the final winner. That is one of the reasons why humans build spacecraft that explore comets in situ. We need more information to advance our understanding of comets and their role in a larger context – the formation, evolution, and history of the outer solar system.

There are two main lines of thought that have dominated during the last decades:

  1. Comets are primitive bodies that formed in their current state 4.6 billion years ago, and they have not been modified much. They are called primordial rubble piles.
  1. Comets consist of material that originally were parts of larger bodies. When these bodies collided violently with each other a huge amount of rubble was formed. Gravity gathered some pebbles into a loosely bound aggregate. Such an aggregate is called a collisional rubble pile. Such collisions occurred in the early solar system and they still happen today. A given comet nucleus could therefore have formed either as recently as one million years ago, or 4.6 billion years ago.

The scientist that consider comets to be primordial rubble piles imagine at least two birth processes, depending on which planetesimal formation scenario they prefer.

1a) Some scientist claim that hierarchical agglomeration dominated planetesial formation. If they are correct the comets we see today are leftovers from that process – the comets consist of smaller planetesimals (usually called cometesimals) that merged at low velocity in the solar nebula. In that sense they are a pile of rubble. A 2 kilometer diameter comet primarily consists of cometesimals with sizes of a few hundred meters, that in turn are built by 10-meter cometesimals, and so on, down to the original small grains. Most of the kilometer-sized objects were consumed by large transneptunians during their growth. However, a few of them managed to avoid being eaten, and we see them today as comets.

1b) Other scientist thing that streaming instabilities mainly are responsible of forming comets. Since the comet is supposed to be primordial it is then necessary that the solar nebula had capacity to form some swarms sufficiently small to form objects with 1-10 kilometer diameter, that managed to go through a gravitational collapse. They are also primordial rubble piles, with the difference that the ”rubble” is dominated by objects with a diameter around a centimeter.

Regardless how the primordial rubble pile formed these scientist agree that the number of objects (small comets and large transneptunians) were so few that violent collisions were rare. Therefore, no collision fragments form that could mix with the primordial rubble piles. These scientist think that the amount of mass in the solar nebula was rather small and the environment was dynamically cold, which means that bodies rarely collide at high speed.

Not all scientist support this view – they refer to other observations or theoretical difficulties that suggest that the solar nebula was massive and dynamically hot. In such an environment comet are inevitably collision rubble piles. However, these scientists do not agree on what took place before the violent collisions.

2a) Some scientist think that hierarchical agglomeration was responsible of building the large transneptunians (like Pluto and Eris). They were the largest objects in a population were all sizes were represented, from the 2300 kilometers of Pluto and Eris, down to objects just being a few hundred kilometers in size. They think that most transneptunians with sizes above 100 kilometers are primordial bodies that have survived since solar system childhood, while bodies in the 50-100 kilometer range have collided efficiently with each other and that the majority of the present small bodies – including comets – are collisional rubble piles. In other words, there has been an efficient collisional cascade. Although some comets may be primordial rubble piles, they are completely outnumbered by collisional rubble piles.

2b) Other scientist think that the first generation planetesimals all were 100-1000 km-class objects, formed through streaming instabilities. Therefore all small objects, including comets with typical diameters of 1-10 kilometers must be collisional rubble piles, formed in a collisional cascade.

It is difficult to tell which of these alternatives that may be considered most popular today. There are no popularity votes or polls among scientists. However, the opinions of individual scientists on a controversial topic does not matter much, not even the opinions among a certain generation of scientists. After all, there is a single objective historical truth – Nature chose a specific route and comets have formed in a specific way. Beliefs and opinions are meaningless – our task is to recover the truth that always been out there. We know by experience that time corrects all mistakes. One hundred years ago, in 1916, Albert Einstein had just published his general theory of relativity and it was motivated to have opinions about the correctness of the theory. There was room for opinions since there were few measurements that could prove or disprove the theory. But during these one hundred years a large number of measurements have been performed in earthly observatories and in space, and it has been possible to make observations of extreme astrophysical object that their behavior has been documented in detail. The technology that made these experiments and observations possible did not exist in 1916. They were developed over time, and over and over Einstein was proven right. Nowadays no serious scientist doubt that Einstein’s general theory of relatively tells us something profound about the properties of Nature, and no-one questions its capability of quantitatively reproducing observed phenomenon with extremely high precision. The doubters of 1916 have been silenced by history. In the same way astronomers 100 years form now – after a number of spacecraft missions to comets that are similar or superior to Rosetta – will look back at the controversies among the scientists of our time with (as always is the case in retrospect) with a faint smile on their lips because they cannot understand how we could be so primitive and childish in our opinions.

Nevertheless, if one tries to select a dominating line of thought, that primarily has reached its status based on the theoretical works that often constitutes the basis of our world view in the absence of concrete observational evidence, I’d say it would be 2b – that comet nuclei are collisional rubble piles and that their parent bodies formed through streaming instabilities. The first reason is that streaming instabilities currently probably should be considered being a more popular scenario than hierarchical agglomeration. Streaming instabilities is an elegant way of avoiding several of the perceived or real bottlenecks and the slowlyness for which the hierarchical agglomeration often has been criticized. The second reason is that the Nice model is very popular today. It states that the giant planets formed rather close to the Sun and that the outer solar system was dominated by a large number of planetesimals gathered in a structure called the primordial disk. The giant planets acquired their current orbits by strong mutual gravitational perturbations that spread the primordial disk planetesimals all over the solar system – some bombarded the Moon (an may explain the presence of the large and comparatively lately formed dark spots that can be seen by the naked eye), others formed the Trojan swarms that share Jupiter’s orbit or were captured as giant planet satellites (which explains the strange orbits for some of these satellites), while yet others formed the Edgeworth-Kuiper belt (which explains its strange structure in detail). The Nice model, in its basic form, hypothesize that the number of planetesimals in the primordial disk was very large – it would be possible to build 35 earths out of that material. With so much mass in an environment that additionally considered to be dynamically hot a collisional cascade is unavoidable.

This is the reason that we chose to use 2b in the ESA press release (see Figure 1) as a representative of ”earlier” comet theories.

Figure 1: The left column of images shows how we often have imagined comet formation before Rosetta. Hierarchical agglomeration first builds pebbles with sizes around a centimeter. Streaming instabilities in the solar nebula then form gigantic swarms of pebbles that merge through gravity to large transneptunians with typical diameters in the range 100-400 kilometers. These then collide with each other – to begin with rather gently so that some of them merge to objects as large as Pluto (2300 km) or the Neptune satellite Triton (2700km) that was captured from the primordial disk. However, collision velocities increase over time and cease to be constructive (in which two smaller objects merge into a large one) and start to become destructive (two smaller objects pulverize each other). In some cases the collision fragments are joined into loosely bound lumps – many scientists see comets as such collision rubble piles. Our new scenario is seen to the right, with one column for large transneptunians and another for small comets. In our opinion the transneptunians form first through streaming instabilities. Remaining material then grows through hierarchical agglomeration to form comets. The growth rate of the comets is so slow that they have time to dissipate the heat generated internally by radioactive decay – therefore they remain very cold and porous. Due to their slow growth much of it takes place after the solar nebula gas has dissipated. In our opinion this gives comets some unique properties – their outer parts are dominated by concentric shells, and they often merge two by two. If comets form in this manner we demonstrate that they are so few in number that they do not collide violently with each other at later times. Comet nuclei are therefore surviving primordial rubble piles that are 4.6 billion years old.

Figure 1: The left column of images shows how we often have imagined comet formation before Rosetta. Hierarchical agglomeration first builds pebbles with sizes around a centimeter. Streaming instabilities in the solar nebula then form gigantic swarms of pebbles that merge through gravity to large transneptunians with typical diameters in the range 100-400 kilometers. These then collide with each other – to begin with rather gently so that some of them merge to objects as large as Pluto (2300 km) or the Neptune satellite Triton (2700km) that was captured from the primordial disk. However, collision velocities increase over time and cease to be constructive (in which two smaller objects merge into a large one) and start to become destructive (two smaller objects pulverize each other). In some cases the collision fragments are joined into loosely bound lumps – many scientists see comets as such collision rubble piles. Our new scenario is seen to the right, with one column for large transneptunians and another for small comets. In our opinion the transneptunians form first through streaming instabilities. Remaining material then grows through hierarchical agglomeration to form comets. The growth rate of the comets is so slow that they have time to dissipate the heat generated internally by radioactive decay – therefore they remain very cold and porous. Due to their slow growth much of it takes place after the solar nebula gas has dissipated. In our opinion this gives comets some unique properties – their outer parts are dominated by concentric shells, and they often merge two by two. If comets form in this manner we demonstrate that they are so few in number that they do not collide violently with each other at later times. Comet nuclei are therefore surviving primordial rubble piles that are 4.6 billion years old.

 

Our new model of comet origins

In our scenario we assume that the primordial disk had a substantially lower mass than in the nominal version of the Nice model. We start off with the lowest mass – about 15 Earth masses – that still is consistent with the overall properties of the Nice model. Therefore, we do not reject the Nice model, but we feel forced to revise the assumption regarding the amount of mass. The reason for this is that we need to avoid an collisional cascade, since we think that the observations by Rosetta excludes that such a process took place. In our opinion 67P/Churyumov-Gerasimenko is a primordial rubble pile.

We demonstrate that the solar nebula initially had such properties that streaming instabilities should have been active. We therefore think that large transneptunians formed very early and we have reasons to claim that their diameters typically were in the range 50-400 kilometers. Since pebbles continuously are consumed in order to build large planetesimals they eventually become too few, compared to the amount of gas, for streaming instabilities to form new pebble swarms. We estimate that this happens when about 13 earth masses have been consumed.

At that point, about 2 earth masses remain in the form of centimeter-sized pebbles. The question is – what happens to those? We claim that this remaining material eventually form comet nuclei. We think that these pebbles start merging to increasingly large units, that is to say, a hierarchical agglomeration process takes place. As previously mentioned, this is a very slow form of growth. In our case it is even slower than in previous works since we start out with an unusually small amount of dust, furthermore, it is only a small fraction of this dust that grows through hierarchical agglomeration. The extremely slow growth is a problem if one want to form planets – but if one wants to form comets it is a necessity.

The thing is that the small pebbles contained a radioactive element called aluminum-26. When this radioactive substance decays heat is being generated. The large transneptunians will therefore experience strong heating and suffer structural, chemical, and mineralogical changes that we think can be seen among those bodies today. However, the comets must be kept extremely cold at all times since only extreme cold can explain why they still are so rich in very volatiles species, and how they managed to maintain an extremely high porosity.

It is much easier for small bodies to dissipate the heat produced (it escapes to space as infrared radiation), than for large bodies. It is therefore good that these cometesimals grew very slowly, since that gives them the chance to cool off.

We estimate that the cometesimals only had reached diameters between 100 meters and 1 kilometer when the solar system reached an age of 3 million years. A few bodies had grown as large as 5-6 kilometers. When the gas in the solar nebula started to dissipate, most comets had therefore not yet grown to their full final size.

The cometesimals that formed in this manner are extremely porous. They have systematically been built by the merger of smaller objects into bigger ones. Meetings between similarly-sized objects were very rare. Instead, meetings between a comparatively large body and a much smaller one have dominated. That affects the shape of the growing objects – they do not look like 67P/Churyumov-Gerasimenko at this stage, that consists of two large lumps (lobes) that attached to each other. These cometesimals are much more spherical, and look more like the individual lobes.

When the gas goes away the conditions for continued growth change completely. The presence of large transneptunians and the absence of drag forces gives rise to a phenomenon called ”viscous stirring”. The practical consequence is that cometesimals now collide with each other at ever increasing velocity (it increases from 0.1 meter per second to tens of meters per second). The rate of change is very slow, but it changes the appearance of the cometesimals.

The somewhat more violent collisions lead to the formation of a shell around the extremely porous cores, that are somewhat less porous. Layer upon layer of compressed material create a stratified outer shell on the cometesimals that resembles the layers in an onion. Another consequence of the viscous stirring is that cometesimals of similar size for the first time collide frequently in space. It is in these type of collisions that objects similar to 67P/Churyumov-Gerasimenko have formed. The collisions take place at sufficiently low velocity that the lobes do not destroy each other, they just gently attach.

We calculate in detail how the viscous stirring changes the collision velocities over time and estimate the number of large transneptunians and comets that collide within their groups and with each other at any given moment. Therefore, we can estimate how the number of objects and their sizes evolve over time. Previous work has shown that the primordial disk existed for about 400 million years. We show that about 350 transneptunians manage to grow to the size of Triton (2700 km) in this time. We also show that the growth phase of comets primarily is over once 20-25 million years have passed. The largest comet-sized objects have diameters of at least 50 kilometers, thus we claim that large comets like Hale-Bopp reached their full size when the solar system was about 25 million years old.

Due to low-velocity mergers and collisions with transneptunians that number of comet nuclei had been heavily reduced at this time. The fact is that they are so few that they do not manage to collide with each other when the viscous stirring has created such high relative velocities that collisions would have been destructive, if they occurred. This is good, because the primordial rubble piles therefore can survive throughout the solar system lifetime so that we can see them as comets.

When 400 million years have passed the giant planets will enter into the primordial disk and destroy it. We calculate in detail how many comets and large transneptunians that are places into the Edgeworth-Kuiper belt and into another population further from the sun called the scattered disk. The scattered disk is considered being the source region of the comets that currently manage to find their way into the inner solar system so that we can see them (67P/Churyumov-Gerasimenko is one of those).

There are several new things in our scenario. The primordial disk has an unusually small mass and is dynamically cold. We have completely separated the comets from the large transneptunians – the comets are not the precursors of transneptunians (as in classical hierarchical agglomeration) and the transneptunians are not the parents of comets (as in a collisional cascade). Instead we view the large transneptunians and the comets as two entirely different populations that formed out of the same building blocks (the centimeter-sized pebbles) but that evolve in different directions due to two completely different processes – in the case of transneptunians through streaming instabilities and in the case of comets through hierarchical agglomeration. It’s not a matter of ”either one or the other” – we believe in a hybrid where both mechanisms are active simultaneously.

Another novelty is that the number of comets may be much smaller than previously thought. Our model has about 100 times fewer comets in the primordial disk compared with previous estimates – we claim there were ”only” about three billion comets with diameters above 2 kilometers. The earlier estimates are based on the number of currently observed comets, combined with a large number of assumptions that lead backward from the inner solar system to the scattered disk, then backward to the days of the primordial disk. Although these estimates have been done ”by the book” we are not fully convinced of their correctness. If our estimate of a substantially lower number of comets is correct, it is easier to understand certain observational studies of the scattered disk, as well as the number of craters on the Moon.

If we are right it also means that rather few comets hit Earth in its childhood. They may have brought less water and organics to our planet than previously assumed. This does not necessarily mean that we need to exclude that comets played a part in the emergence of life on Earth – but we may have to think more in terms of quality rather than quantity.

More about that another time!

Literature

Davidsson, B. J. R., H. Sierks, C. Güttler, F. Marzari, M. Pajola, H. Rickman, M. F. A’Hearn, A.-T. Auger, M. R. El-Maarry, S. Fornasier, P. J. Gutiérrez, H. U. Keller, M. Massironi, C. Snodgrass, J.-B. Vincent, C. Barbieri, P. L. Lamy, R. Rodrigo, D. Koschny, M. A. Barucci, J.-L. Bertaux, I. Bertini, G. Cremonese, V. Da Deppo, S. Debei, M. De Cecco, C. Feller, M. Fulle, O. Groussin, S. F. Hviid, S. Höfner, W.-H. Ip, L. Jorda, J. Knollenberg, G. Kovacs, J.-R. Kramm, E. Kührt, M. Küppers, F. La Forgia, L. M. Lara, M. Lazzarin, J. J. Lopez Moreno, R. Moissl-Fraund, S. Mottola, G. Naletto, N. Oklay, N. Thomas, and C. Tubiana (2016). The primordial nucleus of comet 67P/Churyumov-Gerasimenko. Astronomy & Astrophysics, 592, A63.

OSIRIS imaged Philae in flight

On November 12, 2014, Rosetta’s lander Philae made its historical descent towards the surface of Comet 67P/Churyumov-Gerasimenko, where it bounced twice, and finally came to rest at a third touch-down in a yet unknown location. The OSIRIS camera imaged the bumpy ride.


mosaic5b

Mosaic of OSIRIS Narrow Angle Camera (NAC) images acquired from a distance of about 15.5 km from the surface. The resolution is 28 cm/pixel and the enlarged insets are 17 x 17 m. Credits: ESA/Rosetta/MPS for OSIRIS Team MPS/UPD/LAM/IAA/SSO/INTA/UPM/DASP/IDA


The mosaic of OSIRIS images above covers 30 minutes of action, including the first touch-down. Images taken before and after first contact shows the marks made by the landing gear. All times are GMT. Philae comes flying in from the left at around 0.5 m/s, and bounces the first time at 15:43 GMT. It then takes off towards its second bounce, that took place at 17:25 GMT. It finally came to rest about seven minutes later. We’re all working hard to figure out where it is now!


The scientific imaging system OSIRIS was built by a consortium led by the Max Planck Institute for Solar System Research (Germany) in collaboration with CISAS, University of Padova (Italy), the Laboratoire d’Astrophysique de Marseille (France), the Instituto de Astrofísica de Andalucia, CSIC (Spain), the Scientific Support Office of the European Space Agency (The Netherlands), the Instituto Nacional de Técnica Aeroespacial (Spain), the Universidad Politéchnica de Madrid (Spain), the Department of Physics and Astronomy of Uppsala University (Sweden), and the Institute of Computer and Network Engineering of the TU Braunschweig (Germany). OSIRIS was financially supported by the national funding agencies of Germany (DLR), France (CNES), Italy (ASI), Spain (MEC), and Sweden (SNSB) and the ESA Technical Directorate.

Philae’s landing site selected

On September 10, the ESA spacecraft Rosetta finally entered a circular orbit around Comet 67P/Churyumov-Gerasimenko at a distance of 30 kilometers, after having traveled in a triangular pattern 50-100 kilometers from the nucleus since August 6.


 

A few days later, a decision was made regarding the primary landing site of Philae – area J was selected, placed on the top of the head of the comet nucleus, whose shape resembles that of a duck.


Site_J_Overview

The nucleus of Comet 67P/Churyumov-Gerasimenko resembles a rubber duck, with a “head” and a “body” connected by a thin “neck”. Philae’s primary landing site J is located on the top of the head, next to a circular flat-floored depression. Credits: ESA/Rosetta/MPS for OSIRIS Team MPS/UPD/LAM/IAA/SSO/INTA/UPM/DASP/IDA


The region in question consists of irregular depressions and plateaus, covered by a fine powder. The surface here is relatively planar, contains few blocks, and is thus suitable for landing. However, it is still possible that unpleasant surprises awaits – on September 29 the distance from Rosetta to the comet is decreased to about 19 kilometers, and on October 10 to 10 kilometers, which means that the resolution of the camera OSIRIS will increase a factor three during the coming month. Therefore, we also monitor a secondary landing site – the reserve choice is area C.


Site_J_Closeup

Close-up of landing site J. Credits: ESA/Rosetta/MPS for OSIRIS Team MPS/UPD/LAM/IAA/SSO/INTA/UPM/DASP/IDA


Landing site C is located on the main body, roughly where the duck would have its tail. The area has many similarities with landing site J – it is covered by dust, has relatively few blocks, and consists of planar surfaces surrounded by circular flat-floored depressions. The final decision on landing site will be made on October 14.


Site_C_Closeup

Close-up of landing site C. Credits: ESA/Rosetta/MPS for OSIRIS Team MPS/UPD/LAM/IAA/SSO/INTA/UPM/DASP/IDA


The scientific imaging system OSIRIS was built by a consortium led by the Max Planck Institute for Solar System Research (Germany) in collaboration with CISAS, University of Padova (Italy), the Laboratoire d’Astrophysique de Marseille (France), the Instituto de Astrofísica de Andalucia, CSIC (Spain), the Scientific Support Office of the European Space Agency (The Netherlands), the Instituto Nacional de Técnica Aeroespacial (Spain), the Universidad Politéchnica de Madrid (Spain), the Department of Physics and Astronomy of Uppsala University (Sweden), and the Institute of Computer and Network Engineering of the TU Braunschweig (Germany). OSIRIS was financially supported by the national funding agencies of Germany (DLR), France (CNES), Italy (ASI), Spain (MEC), and Sweden (SNSB) and the ESA Technical Directorate.

Potential landing sites on the comet nucleus

The lander Philae, currently attached to the European Space Agency spacecraft Rosetta, will make its descent towards the surface of the nucleus of Comet 67P/Churyumov-Gerasimenko in early November. Five potential landing sites have now been selected, based on information collected during the first two weeks of observation from a distance of roughly 100 kilometers. This selection is based on flight dynamics constraints (both for orbiter and lander), communication opportunities (between Rosetta and Philae), illumination conditions (battery charging, overheating), surface characteristics (we do not want to land in pits, on boulders, on steep slopes or rough terrain), and last but not least – scientific relevance.


 

Rosetta_OSIRIS_NAC_comet_67P_context_

Overview of the nucleus of Comet 67P/Churyumov-Gerasimenko and location of the five potential landing sites. The nucleus is about 4 kilometers across. Credits: ESA/Rosetta/MPS for OSIRIS Team MPS/UPD/LAM/IAA/SSO/INTA/UPM/DASP/IDA


The potential landing sites have been labeled A, B, C, I, and J. Two of the sites, A and C, are located on the larger of the two lobes. The other three, B, I and J, are located on the smaller lobe. The labeling does not reflect any particular order of importance at this stage. The task now is to study the five sites in more detail, as Rosetta gradually approaches to within 30 kilometers of the nucleus. A decision on a primary landing site, as well as a backup, will be made on September 14. Whether to go for the primary or the secondary site will be determined whilst moving to within 20 kilometers of the nucleus, and a final decision will be made on October 14, roughly a month before the actual landing.


 

As a comet scientist, deeply involved in the Rosetta mission, this is a time of adventure, fascination, and the sense of discovery of something fundamentally important about our Solar System – but it also means long working hours, and not too much sleep. Which is why I have not been able to update this blog as often as I would like to – but with images like these, who can complain!


Rosetta_OSIRIS_NAC_comet_67P_20140816_SiteA

Site A is located on the larger lobe, with a good view of the smaller lobe. The terrain between the two lobes is likely the source of some outgassing. Credits: ESA/Rosetta/MPS for OSIRIS Team MPS/UPD/LAM/IAA/SSO/INTA/UPM/DASP/IDA


Rosetta_OSIRIS_NAC_comet_67P_20140816_SiteB

Site B, within the crater-like structure on the smaller lobe, has a flat terrain and is thus considered relatively safe for landing. However, boulders and illumination conditions may pose a problem. Credits: ESA/Rosetta/MPS for OSIRIS Team MPS/UPD/LAM/IAA/SSO/INTA/UPM/DASP/IDA


 

Rosetta_OSIRIS_NAC_comet_67P_20140816_SiteC

Site C is located on the larger lobe and is well illuminated but rich in surface features that potentially can make a landing risky. Credits: ESA/Rosetta/MPS for OSIRIS Team MPS/UPD/LAM/IAA/SSO/INTA/UPM/DASP/IDA


Rosetta_OSIRIS_NAC_comet_67P_20140816_SiteI

Site I is a relatively flat area on the smaller lobe, but higher-resolution imaging is needed to assess the extent of the rough terrain. Credits: ESA/Rosetta/MPS for OSIRIS Team MPS/UPD/LAM/IAA/SSO/INTA/UPM/DASP/IDA


 

Rosetta_OSIRIS_NAC_comet_67P_20140816_SiteJ

Site J is similar to site I, and also on the smaller lobe, offering interesting surface features and good illumination. Credits: ESA/Rosetta/MPS for OSIRIS Team MPS/UPD/LAM/IAA/SSO/INTA/UPM/DASP/IDA


The scientific imaging system OSIRIS was built by a consortium led by the Max Planck Institute for Solar System Research (Germany) in collaboration with CISAS, University of Padova (Italy), the Laboratoire d’Astrophysique de Marseille (France), the Instituto de Astrofísica de Andalucia, CSIC (Spain), the Scientific Support Office of the European Space Agency (The Netherlands), the Instituto Nacional de Técnica Aeroespacial (Spain), the Universidad Politéchnica de Madrid (Spain), the Department of Physics and Astronomy of Uppsala University (Sweden), and the Institute of Computer and Network Engineering of the TU Braunschweig (Germany). OSIRIS was financially supported by the national funding agencies of Germany (DLR), France (CNES), Italy (ASI), Spain (MEC), and Sweden (SNSB) and the ESA Technical Directorate.

Rosetta’s comet in 3D!

The colorful image of Comet 67P/Churyumov-Gerasimenko is an anaglyph – by looking at it through glasses with a red and a green filter, a three-dimensional image is seen. This is a good way to get a feel for how irregular the terrain actually is.


Anaglyph_1397549300_1397549900_corrected2

The two images used to create this anaglyph were taken by our camera OSIRIS on ESA’s spacecraft Rosetta on August 7, 2014. The images were taken 17 minutes apart to change the viewing geometry, through Rosetta’s motion and the nucleus rotation, which is necessary to create the 3D sensation. Credits: ESA/Rosetta/MPS for OSIRIS Team MPS/UPD/LAM/IAA/SSO/INTA/UPM/DASP/IDA


For those who do not have such glasses – enjoy one of the original images below.


NAC_2014-08-07T20.20.34.562Z_ID30_1397549900_F22_rotated

An original image from OSIRIS used to create the anaglyph above. Credits: ESA/Rosetta/MPS for OSIRIS Team MPS/UPD/LAM/IAA/SSO/INTA/UPM/DASP/IDA


The scientific imaging system OSIRIS was built by a consortium led by the Max Planck Institute for Solar System Research (Germany) in collaboration with CISAS, University of Padova (Italy), the Laboratoire d’Astrophysique de Marseille (France), the Instituto de Astrofísica de Andalucia, CSIC (Spain), the Scientific Support Office of the European Space Agency (The Netherlands), the Instituto Nacional de Técnica Aeroespacial (Spain), the Universidad Politéchnica de Madrid (Spain), the Department of Physics and Astronomy of Uppsala University (Sweden), and the Institute of Computer and Network Engineering of the TU Braunschweig (Germany). OSIRIS was financially supported by the national funding agencies of Germany (DLR), France (CNES), Italy (ASI), Spain (MEC), and Sweden (SNSB) and the ESA Technical Directorate.

 

Meet the heart of Comet 67P/Churyumov-Gerasimenko!

Our new images from the camera system OSIRIS on ESA’s spacecraft Rosetta shows that Comet 67P/Churyumov-Gerasimenko has a spectacularly shaped nucleus! The nucleus consists of two large pieces with different shape, connected at a small contact surface.


shap1

A sequence of 36 processed images of Comet 67P/Churyumov-Gerasimenko taken 20 minutes apart on July 14, 2014, from a distance of about 12,000 kilometers. Credits: ESA/Rosetta/MPS for OSIRIS Team MPS/UPD/LAM/IAA/SSO/INTA/UPM/DASP/IDA


 

One should not look too closely for details in a movie like this. The reasons is clear once we look at one of the original images below. The camera has a limited resolution and the original image consists of a number of squares, or “pixels”, that each have recorded a certain light intensity. We do not know how the nucleus looks like within each pixel – but we can guess!


Abbildung 1 a

An original picture from OSIRIS before image processing. Credits: ESA/Rosetta/MPS for OSIRIS Team MPS/UPD/LAM/IAA/SSO/INTA/UPM/DASP/IDA


 

During so-called image processing, mathematical algorithms are used in an attempt to re-create how an object really looks like, before it got smeared out by the pixels. Such algorithms are good at re-creating lost information, but they are not perfect. Real surface structures may have been lost completely, while false features that do not exist in reality may have been added.


Abbildung 1 b

A processed image from OSIRIS. Credits: ESA/Rosetta/MPS for OSIRIS Team MPS/UPD/LAM/IAA/SSO/INTA/UPM/DASP/IDA


 

The only way to find out how the comet surface really looks like is to get closer – and in a short while Rosetta will be much closer to the comet!


The scientific imaging system OSIRIS was built by a consortium led by the Max Planck Institute for Solar System Research (Germany) in collaboration with CISAS, University of Padova (Italy), the Laboratoire d’Astrophysique de Marseille (France), the Instituto de Astrofísica de Andalucia, CSIC (Spain), the Scientific Support Office of the European Space Agency (The Netherlands), the Instituto Nacional de Técnica Aeroespacial (Spain), the Universidad Politéchnica de Madrid (Spain), the Department of Physics and Astronomy of Uppsala University (Sweden), and the Institute of Computer and Network Engineering of the TU Braunschweig (Germany). OSIRIS was financially supported by the national funding agencies of Germany (DLR), France (CNES), Italy (ASI), Spain (MEC), and Sweden (SNSB) and the ESA Technical Directorate.

OSIRIS: First glimpse of the comet nucleus!

Up to just a few days ago, the target of ESA’s Rosetta mission, Comet 67P/Churyumov-Gerasimenko, was just a dot in the sky, barely distinguishing itself from the stars by displaying a small temporary dust coma. But now Rosetta is getting so close to the comet, 40 000 kilometers – about a tenth of the distance between Earth and the Moon – that the OSIRIS camera starts to resolve the nucleus. The comet nucleus is still just a couple of camera pixels across, but as seen in the movie below, there is a hint of nucleus irregularity. The nucleus size and shape changes slightly, while it is rotating with its 12.4 hour period. From now on, the comet nucleus will just grow in size until it fills the entire field of view of the Narrow Angle Camera (NAC) in mid August. Stay tuned for more cool pictures from OSIRIS!


zoom5-100ms

First resolved images of comet 67P/Churyumov-Gerasimenko show the nucleus rotating with a rotation period of 12.4 hours. This set of 36 images was obtained by OSIRIS’ narrow angle camera (NAC) on June 27th and June 28th and covers one such period. © ESA/Rosetta/MPS for OSIRIS Team MPS/UPD/LAM/IAA/SSO/INTA/UPM/DASP/IDA


The scientific imaging system OSIRIS was built by a consortium led by the Max Planck Institute for Solar System Research (Germany) in collaboration with CISAS, University of Padova (Italy), the Laboratoire d’Astrophysique de Marseille (France), the Instituto de Astrofísica de Andalucia, CSIC (Spain), the Scientific Support Office of the European Space Agency (The Netherlands), the Instituto Nacional de Técnica Aeroespacial (Spain), the Universidad Politéchnica de Madrid (Spain), the Department of Physics and Astronomy of Uppsala University (Sweden), and the Institute of Computer and Network Engineering of the TU Braunschweig (Germany). OSIRIS was financially supported by the national funding agencies of Germany (DLR), France (CNES), Italy (ASI), Spain (MEC), and Sweden (SNSB) and the ESA Technical Directorate.

 

Organics in space

This article was originally posted on the blog Dinner Table Science were I was guest blogging – please visit and follow Rachel’s blog, it is great!


Life, as we know it, would not have been possible without the carbon atom. The scientific discipline dealing with all the molecular relationships that the carbon atom is getting itself into – organic chemistry – is essential for understanding how living organisms function and evolve. We take it for granted that organic chemistry is flourishing on Earth, because it is teeming of life, but only in the last few decades have we come to realize that such processes also are common far beyond our own planet – in the depths of space. No form of extraterrestrial life has been discovered so far, but a surprisingly rich variety of organic compounds has been found within the Solar System, as well as in the interstellar medium. None of these organic molecules have a biological origin but some may, or may not, have been prebiotic, i.e., involved in the processes that eventually led to the emergence of life on our planet.


Organic molecules are found in many different Solar System objects or space environments, but here we will focus on two of them – a type of meteorite called a carbonaceous chondrite, and the interstellar medium. After reviewing what we know about these organic substances, we will also discuss the processes believed to have created them.

fig1

The Murchison meteorite is a carbonaceous chondrite. It is one of our most important sources of information on organics from space due to its large mass (more than 100 kg) and the fact that it was recovered right after it fell, and has suffered a minimum of terrestrial contamination. This picture shows a piece of Murchison at the The National Museum of Natural History (Washington). Original image: http://en.wikipedia.org/wiki/File:Murchison_crop.jpg

 


Carbonaceous chondrites

Most of the meteorites that impact Earth, almost 90%, are so-called chondrites. They got their name because they are rich in chondrules, a type of millimeter-sized grain formed in huge numbers 4.57 billion years ago during the earliest phase of Solar System history. They still contain these ancient particles because the chondritic meteorite parent bodies never melted (these 10-100 km parent bodies later broke up in devastating collisions, and the chondritic meteorites are tiny fragments from such collisions). This distinguishes the chondritic meteorites from achondritic meteorites (8% of the falls) and iron meteorites (2% of the falls) that both originate from parent bodies that once were heated by radioactive decay to the point that they actually melted and differentiated, e.g. separated into a rocky mantle and a metallic core. Such melting erased all memory of previous history, and that is why chondritic meteorites are so valuable – they can tell us about the time before the formation of the parent bodies (most of which eventually were merging to form the planets).


Most chondritic meteorites are so-called ordinary chondrites that are related to the rocky S-type asteroids in the inner main asteroid belt. This region was generally too warm to allow molecular compounds with a low boiling point to condense into solids. However, some of the meteorites are carbonaceous chondrites, believed to be related to the more distant C-type asteroids from the outer main asteroid belt. They formed in conditions sufficiently cold to allow condensation of very volatile species – they are therefore rich in water (up to 20% by mass) and they also contain organic molecules that are rare or absent in the inner Solar System.


The carbonaceous chondrites got their name because they are unusually dark – they look like charcoal. The name is actually misleading, because the dark color is not due to carbon, but due to iron, an atom that is very efficient in absorbing light. In ordinary chondrites, the iron is gathered into small metallic particles mixed with the chondrules (we say that the iron is reduced), leaving the rocky material virtually iron-free and thus fairly bright in color. In carbonaceous chondrites, the iron is finely distributed throughout the rocky material on an atomic level (we say that the iron is oxidized), which makes the entire rock an efficient light absorber, thus being dark.


The typical carbonaceous chondrite contains only about 2-5% carbon by mass. However, this organic material is amazing, particularly the 25% that is referred to as “extractable organic matter” that is either liquid or solid at room temperature. In decreasing order of abundance the extractable organic matter consists of the following cocktail, of which a selection is described below – carboxylic acids, sulfonic acids, amino acids, sugars, urea, aliphatic and aromatic hydrocarbons, ketones, ammonia, alcohols, purines and pyrimidines. The remaining 75% is called “macromolecular material” and is a solid substance with an extremely complex composition. In some cases, the organics in meteorites is partially terrestrial contaminations. However, the risk of contamination is low if meteorites are recovered directly after a fall, and in most cases the meteoritic organics have such unusual concentrations of the isotopes carbon-13, nitrogen-15 and hydrogen-2 (deuterium), that a terrestrial origin can be excluded. Thus, the compounds discussed below are definitively from space.


In order to understand how the macromolecular material looks like, we need to know how carbon atoms interact with their own kind and with other atoms. A carbon atom can bind itself to up to four other atoms simultaneously. Often, carbon atoms form linear chains of various length. A given carbon atom within the chain then connects with two of its carbon neighbors, meaning that it can afford to connect also with two other atoms, typically hydrogen (but sometimes oxygen, nitrogen or other atoms). The carbon atom sitting at the end of a chain only connects with one other carbon, allowing it to attach three hydrogen atoms to it. These chain-like structures are called aliphatic hydrocarbons. However, it is also common that six (and sometimes five) carbon atoms form a ring. Here, a given carbon atom uses two of its connections to bind to the first of its carbon neighbors, and one for the second, leaving space for a single foreign atom (often hydrogen) to attach itself externally to the ring. Such ring-like structures are called aromatic hydrocarbons. Rings can also attach to each other, so that two carbon atoms simultaneously are members of two rings. Molecules that contain several such rings are called polycyclic aromatic hydrocarbons (or PAHs).


The macromolecular material in carbonaceous chondrites has proven to be a gigantic web, where aromatic rings use aliphatic chains to connect to each other. Often there are single rings that have replaced one or several of their external hydrogen atoms with an aliphatic chain – typically with 2-4 carbon atom links – in order to connect to another aromatic ring located farther away. However, it is not unusual that two, three or four rings form a little aromatic island, that connects itself to other islands through the aliphatic bridges. The fraction of macromolecular carbon that is aromatic is about 60-70% for Murchison, about 70-80% for Orgueil and almost 100% for Tagish Lake (these are three different carbonaceous meteorites). A typical elemental composition of the macromolecular material is about 70 hydrogen atoms (H), 12 oxygen atoms (O), three nitrogen atoms (N) and two sulphur atoms (S), for every 100 carbon atoms (C).


The extractable organic matter is dominated by carboxylic acids – these are basically aliphatic chains where one carbon atom at the end of the chain has replaced two of its hydrogen atoms with a single oxygen atom, and replaced the last hydrogen atom with a hydroxyle group consisting of an oxygen atom with a hydrogen attached to it (thus there is a COOH group). If both ends of the chain has COOH groups, the molecule is called a dicarboxylic acid. Examples include formic acid (HCOOH) used by ants as a venom, acetic acid (CH3COOH) used in cooking in diluted from under the name vinegar, butyric acid (C3H7COOH) that gives rancid butter its unpleasant smell, and valeric acid (C4H9COOH) that is named after the valerian herb (Valeriana officinalis) that produces this molecule. They are all found in carbonaceous meteorites, that often contain carboxylic acids with up to ten carbon atoms.


If a carboxylic acid has one of its hydrogen atoms in the aliphatic chain replaced by the amino group NH2, it is called an amino acid. Amino acids are fundamental to life, because they are the building blocks of proteins. Humans and other animals need to eat proteins, and the body break them down into their amino acid constituents, that are then used by cells to build other proteins (a process called translation) that we need to function. To find amino acids in meteorites is extremely fascinating, just because they play such a central role in the chemistry of living organisms.


More than 70 different amino acids have been identified in carbonaceous meteorites. Some of these meteorites, like Murchison, Orgueil and Ivuna are rather rich in amino acids. Others, like Tagish Lake, have extremely low abundances of amino acids. Murchison contains eight of the protein amino acids, eleven that are biologically common, and several others that are not used by terrestrial organisms. The five most common, in decreasing order of abundance, is glycine (NH2[CH2]COOH), alpha-aminoisobutyric acid (NH2[C3H6]COOH), D-alanine and beta-alanine (NH2[C2H4]COOH), and isovaline (NH2[C4H8]COOH), where the chemical formulae have been written to highlight the amino and carboxyl groups. Here, the prefixes “alpha” and “beta” is a way to tell which carbon atom the amino group is attached to.


Most amino acids have so-called chirality, which means that there are two variants of each molecule (called enantiomers), that have the same chemical composition but geometrically are mirror images of each other. They are distinguished through the prefixes L and D such as in L-alanine and D-alanine. All proteins built by translation contain L enantiomers. In carbonaceous chondrites both enantiomers appear to be equally common, although some controversial studies show that there may be a slight L-excess for certain amino acids like alanine, proline and leucine.


Aromatic hydrocarbons are not only found in the macromolecular material, but also in the extractable organic material. The most common compounds are the PAHs fluoranthene and pyrene. They both have the formula C16H10 but are structurally different – flouranthene consists of three standard rings with six carbon atoms, joined by a ring containing just five carbon atoms, while pyrene is made of four standard rings.

fig2

The structural formula of pyrimidine, showing how carbon (C) and nitrogen (N) atoms form a ring, to which a number of hydrogen (H) atoms are attached. Original image: http://en.wikipedia.org/wiki/File:Pyrimidine_2D_aromatic_full.svg

 

The really interesting thing starts when the carbon atoms in aromatic rings are replaced by nitrogen. If the starting point is a single six-atom ring (called benzene if all atoms are carbon), and two specific carbon atoms are exchanged with nitrogen, a substance called pyrimidine (C4H4N2) is formed. By replacing hydrogen atoms by amino groups or oxygen atoms, a variety of molecules can be formed, including the nucleobases cytosine (C), thymine (T) and uracil (U), that are basic building blocks in DNA and RNA. The pyrimidine uracil has been found in carbonaceous chondrites.

fig3

The structural formula of uracil. The aromatic ring is here somewhat abstract since corners are meant to indicate the location of a carbon atom (sometimes with a hydrogen atom attached to it), while only nitrogen and oxygen atoms, with associated hydrogen atoms, are shown explicitly. Original image: http://en.wikipedia.org/wiki/File:Uracil.svg

 

If the starting point is a six-atom ring joined to a five-atom ring, and two specific carbon atoms in each ring are replaced with nitrogen, a compound called purine (C5H4N4) is obtained. As before, the replacement of hydrogen atoms with amino groups and oxygen atoms gives rise to a variety of molecules, including two other nucleobases that are found in DNA – adenine (A) and guanine (G). Both adenine and guanine has been found in carbonaceous chondrites, along with other purines, such as xanthine and hypoxanthine.

fig4

The structural formula of various kinds of purines. Adenine, guanine, hypoxanthine and xanthine have been found in carbonaceous chondrites. Original image: http://en.wikipedia.org/wiki/File:Purines.svg

 

It is therefore clear that carbonaceous chondrites contain a variety of fairly complex organic molecules. Comet nuclei are likely to be as rich or even richer in such compounds, although we know much less about comets than meteorites since actual samples of comet material is restricted to very small amounts, collected by the Stardust spacecraft in the coma of Comet 81P/Wild 2 and brought back to Earth. Both carbonaceous chondrites and comets bombarded the young Earth, thereby bringing organic substances to the inner region of the Solar System, where such compounds initially may have been rare. The possibility that these organics were involved in the formation of life on Earth is a fascinating thought. But what is the origin of these compounds – where did they form and how? To answer that question, we must leave the Solar System and head out into interstellar space.


The interstellar medium

The space between the stars in our galaxy, the Milky Way, is not empty – about 90% of the galactic mass is bound in stars, while the rest forms an extremely thin mixture of gas and solid dust particles that fill the space between the stars – the interstellar medium. About 98-99% of the mass is hydrogen and helium, while the remaining fraction is shared between all heavier elements. Among these, oxygen is the most common element by number, followed by carbon, neon, and nitrogen. These elements mainly exist as unbound atoms in the gas phase, while the solid grains primarily consist of silicates and sulfides rich in oxygen, magnesium, silicon, iron and sulphur (these are the ten most common chemical elements in the universe, by number).


In places where the interstellar medium is particularly dense – the molecular clouds – atoms in the gas phase form small molecules, primarily molecular hydrogen (H2), carbon monoxide (CO), and molecular nitrogen (N2), but also water (H2O), carbon dioxide (CO2), ammonia (NH3), methane (CH4), and methanol (CH3OH). Over time, some of these gases will condense on top of the grains, thus forming mantles of ice that surround the rocky cores.


When such ice is exposed to ultraviolet radiation from nearby stars, it gets damaged. Molecules are cut into small pieces called radicals. These are extremely reactive, but due to the extreme cold (typically 10K or -260C) the radicals have little mobility and do not manage to get in physical contact with each other. Over time, large deposits of radicals are built up within the ice. Only a small amount of heating, perhaps due to rare collisions between icy grains, is sufficient to trigger an explosive chain reaction, were radicals unite to form a variety of complex organic molecules. Many of these leave the grain surfaces and can be observed as free molecules in the interstellar gas, while others remain on the grain surfaces.


This process is at least partially responsible for the rich variety of organic molecules that has been observed in interstellar space. Observations are made with radio telescopes, that pick up the long-wavelength radiation that the molecules emit when they change their rotation or vibration rates. More than 150 molecular compounds have been identified in the interstellar medium, of which a third contain six atoms or more. Some large molecules that have been identified include propylene (CH3CHCH2), methyltriacetylene (CH3C6H), vinyl alcohol (C2H3OH), acetic acid (CH3COOH), ethylene glycol (HOCH2CH2OH), cyanopentaacetylene (HC11N), and acetamide (CH3CONH2).


The processes taking place in the interstellar medium can be reproduced in laboratories. A mixture of ice (for example, water, carbon monoxide, carbon dioxide, ammonia, and methanol in proportions expected in interstellar ice) is deposited on a 10K substrate, and the mixture is irradiated by ultraviolet radiation and then slowly heated to trigger the chain reaction. An organic residue is thus formed, sometimes called “yellow stuff”. The material is particularly rich in carboxylic acids and hexamethylenetetramine (C6H12N4). In one particular experiment, no less than 16 amino acids where identified in this yellow stuff. These included glycine, alanine, sarcosine, valine and serine. In these samples both enantiomers of each amino acid were equally common, to within measurement uncertainties.


Stellar and planetary systems form when interstellar gas and dust collapse due to its self-gravity, in regions where the interstellar medium has become exceptionally dense. According to the “interstellar parent-body hypothesis” the organic compounds seen in carbonaceous chondrites are interstellar organics that survived the turmoil of Solar System formation. That is to say, these substances did not primarily form here, and at least a fraction of the material must have avoided heating to the point where they would have disintegrated into their atomic constituents. The material may have been processed or altered in various ways, but the key idea is that the carbonaceous chondrite parent bodies contained complex organics already when they formed. The very unusual isotopic composition that characterize these organics are often interpreted as evidence of an interstellar origin.


Although the carbonaceous chondrite parent bodies formed sufficiently late not to melt (perhaps 1-2 million years after differentiated bodies, at a time when the short-lived radioactive heat source aluminum-26 almost had vanished), they still experienced mild warming. The temperature was sufficiently high to melt ice within the parent body, and allowing liquid water to percolate through the granular interior. This has led to various levels of so-called aqueous alteration – characteristic changes of the mineralogical composition of the meteorite caused by liquid water. The presence of liquid water has also modified the composition of the organics. It appears increasingly unlikely that the organics we see today in carbonaceous chondrites were formed from scratch during aqueous alteration – they must have had a long and complex previous evolutionary history that started in interstellar space.


The exploration of organics in space has merely begun. The presence of complex organic molecules in distant asteroids and comet nuclei are strong reasons for performing sample return missions to such bodies. The answers to some of our most profound questions about our existence may lay buried within these ancient survivors of planetary formation – how did the Solar System form, what kind of material rained down on the young Earth, and is it possible that life got a jump start thanks to organics from space?

We just have to go and have a look.


Literature

Gilmour, I. (2003). Structural and isotopic analysis of organic matter in carbonaceous chondrites. Treatise on Geochemistry, 1, 269-290.

Herbst, E., van Dishoeck, E. F. (2009). Complex organic interstellar molecules. Annual Review of Astronomy and Astrophysics, 47, 427-480.

Muñoz Caro, G. M., Meierhenrich, U. J., Schutte, W. A., Barbier, B., Arcones Segovia, A., Rosenbauer, H., Thiemann, W. H.-P., Brack, A., Greenberg, J. M. (2002). Amino acids from ultraviolet irradiation of interstellar ice analogues. Nature 416, 403-406.

Comet 67P/Churyumov-Gerasimenko wakes up as ESA’s Rosetta spacecraft approaches!

I was at the OSIRIS Full Team meeting held at the Max Planck Institut für Sonnensystemforschung in Göttingen, Germany, last week. We had a great meeting, and the good news are piling up – the spacecraft Rosetta performs well, our imaging camera system OSIRIS is fully operational (as are all the other instruments), orbit manoeuvres are successfully executed to enable Rosetta to rendezvous with the comet in early August, and we have already started to do science.

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Between March 24th and May 4th, Rosetta approached comet 67P/Churyumov-Gerasimenko from a distance of around 5 million to 2 million kilometers. This sequence of images shows the comet’s movement against the background star field during this time. Rosetta (and the comet) are between 640 and 610 million km from the Sun. The comet is seen to develop a dust coma as the sequence progresses, with clear activity already visible in late-April. Exposure times are 720s for each image, taken with the OSIRIS/NAC through the Orange filter. credits: ESA/Rosetta/MPS for OSIRIS Team MPS/UPD/LAM/IAA/SSO/INTA/UPM/DASP/IDA

 

First of all, we have detected the nucleus of Comet 67P/Churyumov-Gerasimenko and are tracking its motion. Secondly, the lightcurve is being monitored regularly, which has allowed us to measure a 12.4 hour rotation period of the nucleus. The lightcurve is a periodic variation in the observed brightness of the nucleus. The variations arise since the nucleus is not spherical but irregular, so that the amount of solar light that is reflected by the nucleus towards the spacecraft is changing with time as the nucleus rotates. The third discovery is that the comet nucleus – which was dormant and quiet at our first observations in late March – now has become active.

Comet activity means that the ice in the nucleus surface layers has become heated sufficiently by sunlight to sublimate, i.e., turn directly to vapor without first becoming liquid. At these distances, at the time of writing 4.03 AU from the Sun, the temperature is too low to allow water ice to sublimate. Instead, more volatile substances like carbon monoxide and carbon dioxide are responsible for the activity. OSIRIS do not see these gases directly. However, the sublimation also liberates a large amount of micrometer-sized dust grains that are entrained in the gas as it rushed into space. OSIRIS detects the solar light that is reflected by this dusty coma, that currently measures about 2600 kilometers across.

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The OSIRIS Team. Yours truly is marked with the arrow. Credits: MPS

OSIRIS on Rosetta has imaged Comet 67P/Churyumov-Gerasimenko!

As a member of the OSIRIS Science Team I am happy to announce that our camera OSIRIS, that flies on ESA’s spacecraft Rosetta, now has imaged the target of its ten year long journey – Comet 67P/Churyumov-Gerasimenko!

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Comet 67P/Churyumov-Gerasimenko in constellation Ophiuchus. This image taken with the Wide Angle Camera on March 20 shows a wide field 25 times larger than the diameter of the full moon. The color composite shows a background of hydrogen gas and dust clouds in the constellation Ophiuchus. The white box indicates the position of the close-up taken with the Narrow Angle Camera (below). The images were taken from about 0.03 AU distance to the comet. Rosetta was at a distance of approx. 4.4 AU from Earth. Image credit: ESA ©2014 MPS for OSIRIS Team MPS/UPD/LAM/IAA/SSO/INTA/UPM/DASP/IDA

Rosetta was launched in March 2004. The purpose of the spacecraft is to explore, in situ, what happens to a comet nucleus when it approaches the Sun from a very large distance, gradually is heated and therefore becomes active. Therefore, Rosetta first had to get very far out in the Solar System. The spacecraft swung by Earth three times, and Mars on one occasion, so that the gravitational perturbations from these planets gradually could make Rosetta’s orbit around the Sun wider. On its way, the spacecraft also passed near to two asteroids – (2867) Steins in September 2008 and (21) Lutetia in July 2010. I June the following year, Rosetta had come so far from the Sun that its solar panels no longer managed to generate the electric power necessary to keep the entire spacecraft up and running. Therefore, Rosetta was put in hibernation and all available power was used to heat the instruments to prevent them from break by freezing. The ground control had no contact with Rosetta at all.

In October 2012 Rosetta was farthest from the Sun, no less than 5.3 AU (one astronomical unit, 1 AU, is the mean distance between Sun and Earth, and corresponds to 150 million kilometers). It means that Rosetta was beyond the orbit of Jupiter, that is located 5.2 AU from the Sun. Two and a half years after Rosetta entered hibernation, on January 20, 2014 to be precise, it was time for the spacecraft to wake up. It was an enormous relief when the signals from Rosetta reached the ground control! After the wake-up, careful checks were made to make sure Rosetta was feeling well after its long sleep. We are now at a stage where the scientific instruments are switched on one by one, to see how they have coped with the hibernation. OSIRIS was switched on last week, and has now taken its first images of the comet – the camera works beautifully! We will therefore be ready when Rosetta reaches the comet in August this year, at a distance of about 4.5 AU from the Sun.

OSIRIS WAC

OSIRIS is the camera system on Rosetta. It actually consists of two different telescopes. One of them is called the Wide Angle Camera (WAC) and has a rather large field of view since it will be used to image the comet coma, the cloud of gas and dust that the comet nucleus surrounds itself with (see a previous post on comets). The camera has 14 different filters – glass plates with a special composition and surface coating that makes them transparent to light only at specific wavelengths. These filters are manufactured in Sweden and is the Swedish hardware contribution to OSIRIS. Seven of these filters are so-called narrowband filters – they are transparent only at very strict wavelength regions corresponding to the wavelength were seven different molecular fragments (radicals) emit light when they are illuminated by the Sun. These radicals are CS (a compound consisting of carbon and sulphur), the hydroxyle radical OH and the oxygen atom O (these are formed when the ultraviolet light of the Sun break down water molecules), NH and NH2 (compounds of nitrogen and hydrogen), CN (the cyano radical, consisting of carbon and nitrogen), and the sodium atom (Na), that can be outgassed by dust grains that are strongly heated by sunlight.

The dust grains in the comet coma will reflect sunlight, and some of this light will find its way through the narrowband filters. This is not good, since we will use the intensity of the light to calculate the abundances of radicals and atoms in the coma. Since the dust grains contribute with light, that does not originate from within the gas at all, the risk is that we overestimate the abundance of gas. Therefore, the WAC also has seven filters that is transparent to light just next to the wavelength regions of the narrowband filters. In this way, the contribution of the dust grains to the measured light can be estimated, and compensated for when determining the gas abundance. Four of these filters are transparent in the ultraviolet wavelength region (for example, a filter called UV375), while the others are located in the green, yellow and red wavelength regions.

The image above is really three different WAC images, taken through different filters. The red filter was used during an exposure that lasted one minute. The green filter was used during an equally long exposure. Finally, the UV375 filter was used three times with a total exposure time of nine minutes. By combining these images, the color photo above could be constructed.

OSIRIS NAC

The second camera is called the Narrow Angle Camera (NAC). It has a smaller field of view than the WAC, but is capable of resolving objects that are five times smaller than the ones the WAC manages to resolve. This camera will primarily be used to study the comet nucleus. This camera also has Swedish filters, but with quite different properties – a mixture of broadband filters in different parts of the visible wavelength region to make a rough characterization of the comet spectrum, and a number of filters that will be used to search for specific minerals, like pyroxene, hematite and hydrated silicates.

The figure below shows a picture taken with the NAC, and corresponds to the white square in the picture above. The strongly magnified picture shows a globular cluster called Messier 107 (or M107), as well as the comet nucleus within the small circle. It is still far too distant to be seen in detail, and is only a dot in the sky. But day by day Rosetta is closing in on the comet and soon we will be able to see how it looks like up close!

 

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Comet 67P/Churyumov-Gerasimenko in constellation Ophiuchus. A zoom into an image taken with the Narrow Angle Camera on March 21. The comet is indicated by the small circle, next to the bright globular star cluster M107. The images were taken from about 0.03 AU distance to the comet. Rosetta was at a distance of approx. 4.4 AU from Earth. Image credit: ESA ©2014 MPS for OSIRIS Team MPS/UPD/LAM/IAA/SSO/INTA/UPM/DASP/IDA

For ESAs press release click here.